Boundary values of an analytic function and the Tchebycheff by Walsh J.L.

By Walsh J.L.

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Nobel Lectures, Physics 1901–1921, Elsevier Publishing Company, Amsterdam, 1967. 15. (a) P. J. Stephens, Adv. Chem. , 1976, 35, 197; (b) A. D. Buckingham and P. J. Stephens, Ann. Rev. Phys. , 1966, 17, 399. 16. R. Serber, Phys. , 1932, 41, 489. 17. C. H. Henry, S. E. Schatterly and C. P. Slichter, Phys. , 1965, A137, 583. 18. J. Michl, Tetrahedron, 1984, 40, 3845. 19. B. Briat, D. A. Schooley, R. Records, E. Bunnenberg and C. Djerassi, J. Am. Chem. , 1967, 89, 6170. 20. (a) P. N. Schatz, A. J. McCaffery, W.

Cos g? 746 == == R ðÆÞ ¼ ƽfePc ðlPc Þ R12 g=ð4hފsin a sin g sin t == == == == == == ð3:3Þ == == == e ðÆÞ ¼ ePc Æ ½ðlPc Þ2 =4p20 ðR12 Þ3 Šðsin a sin g cos t þ 2cos a cos g Þ ð3:4Þ It should be noted that the angle t is always taken in an anticlockwise direction when the system is viewed from Pc1 to Pc2 and that the notations plus and minus denote in-phase and out-of-phase transitions, respectively. 14. In this calculation, the absolute configuration was arbitrarily chosen to be the (6aS, 11bR) form.

Chem. Soc. 1974, 96, 7352. ] result, this compound exhibits very intense CD signals of opposite sign and almost equal intensity in the 1Bb band region. 4 the inflection point of the CD curve does not match the absorption maximum. This can be rationalised by considering point dipole moments for the long axis-polarised 1Bb transition placed at the centre of each anthracene moiety. 10), has a value that is definitely positive. 1 [Reprinted with permission from J. Am. Chem. , 1975, 97, 5345. ] of the a state at longer wavelength are in phase, while those of the b state at shorter wavelength are out of phase.

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