By Walsh J.L.
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Extra info for Boundary values of an analytic function and the Tchebycheff method of approximation
Nobel Lectures, Physics 1901–1921, Elsevier Publishing Company, Amsterdam, 1967. 15. (a) P. J. Stephens, Adv. Chem. , 1976, 35, 197; (b) A. D. Buckingham and P. J. Stephens, Ann. Rev. Phys. , 1966, 17, 399. 16. R. Serber, Phys. , 1932, 41, 489. 17. C. H. Henry, S. E. Schatterly and C. P. Slichter, Phys. , 1965, A137, 583. 18. J. Michl, Tetrahedron, 1984, 40, 3845. 19. B. Briat, D. A. Schooley, R. Records, E. Bunnenberg and C. Djerassi, J. Am. Chem. , 1967, 89, 6170. 20. (a) P. N. Schatz, A. J. McCaﬀery, W.
Cos g? 746 == == R ðÆÞ ¼ Æ½fePc ðlPc Þ R12 g=ð4hÞsin a sin g sin t == == == == == == ð3:3Þ == == == e ðÆÞ ¼ ePc Æ ½ðlPc Þ2 =4p20 ðR12 Þ3 ðsin a sin g cos t þ 2cos a cos g Þ ð3:4Þ It should be noted that the angle t is always taken in an anticlockwise direction when the system is viewed from Pc1 to Pc2 and that the notations plus and minus denote in-phase and out-of-phase transitions, respectively. 14. In this calculation, the absolute conﬁguration was arbitrarily chosen to be the (6aS, 11bR) form.
Chem. Soc. 1974, 96, 7352. ] result, this compound exhibits very intense CD signals of opposite sign and almost equal intensity in the 1Bb band region. 4 the inﬂection point of the CD curve does not match the absorption maximum. This can be rationalised by considering point dipole moments for the long axis-polarised 1Bb transition placed at the centre of each anthracene moiety. 10), has a value that is deﬁnitely positive. 1 [Reprinted with permission from J. Am. Chem. , 1975, 97, 5345. ] of the a state at longer wavelength are in phase, while those of the b state at shorter wavelength are out of phase.